Molecules are not static. Single bonds can rotate causing the shape of a molecule to change. This is known as changing the conformation of a molecule. Some conformations are more favourable than others, these are sometimes called conformers. Other conformations are disfavoured. They are the barrier to rotation or a transition state between conformers. This summary looks at the conformations of simple alkanes.

The classic, what kind of isomer do I have here flowchart. There are a number of these online but it is useful. Surprisingly, hard to fit onto one page (nicely).